Personly I was in tears when I first listened to the music in PSIII when you start the game as Rhys.
Second would have to be Age of fables. I can't even listen to "her last breathe" anymore without breaking down in tears. Requim of Lutz is nice meditation music. Thray.. my ears cherish you the most. I remember sitting on my bed as a kid with a cassete player that was bigger than I was and recording Thray on my television. I wore that tape down so quickly.. I wouldn;t ever stop listening to it. -sigh- Good times.. Good times. =]